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1 article(s) from Beyraghdar Kashkooli, Arman

18-Hydroxydolabella-3,7-diene synthase – a diterpene synthase from Chitinophaga pinensis

Jeroen S. Dickschat,
Jan Rinkel,
Patrick Rabe,
Arman Beyraghdar Kashkooli and
Harro J. Bouwmeester

Beilstein J. Org. Chem. 2017, 13, 1770–1780, doi:10.3762/bjoc.13.171

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Scheme 1: Germacrene A (1) and its Cope rearrangement to β-elemene (2).

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Figure 1: In vitro terpene synthase activity of the investigated recombinant enzyme from C. pinensis, showing...

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Scheme 2: Product obtained from the diterpene synthase from C. pinensis. (A) Structure of (1R,3E,7E,11S,12S)-...

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Figure 2: Determination of the absolute configuration of 3. (A) Partial HSQC spectrum of unlabelled 3 showing...

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Figure 3: Determination of the absolute configuration of 3. (A) Partial HSQC spectrum of unlabelled 3 showing...

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Figure 4: Assignment of H6α and H6β of 3. (A) Partial HSQC spectrum of unlabelled 3 showing the region for C6...

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Figure 5: Partial ¹³C NMR spectra of A) unlabeled 3, B) (¹³C₁)-3 arising from incubation of HdS and GGPPS wit...

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Figure 6: Transient expression of 18-hydroxydolabella-3,7-diene synthase (HdS) in Nicotiana benthamiana. Tota...

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Published 23 Aug 2017

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